If you have watched the TV show called Oak Island, you'll see that they are digging up wooden beams in pristine condition that have been in ground for hundreds of years. Last week, they pulled up a post that you could see the circular saw marks created when the beam was originally created in the 1800's.
Wood does not rot in the ground. It takes a combination of things for it to rot, with air being a big part of that. When they do rot, it's at the surface of the ground where water is allowed to puddle and sit for an extended period of time. If you build your barn so that water runs away from the building, it should easily last a hundred years or more.
I feel the reason some companies laminate three 2x6's together is for speed in notching those posts. I've dug through too many piles of treated 2x6's to believe that they are straighter then 6x6's. I've also seen them bend, twist and shrink after they have dried out. The shrinking is what gives me the most problems when I build a deck for a client. Out of a hundred boards, several will shrink in length half to 3/4's of an inch in six months. Several will twist or bow regardless of being screwed into the joists every 2 feet. I tell my clients that it's because of the way it's currently treated, and there is no predicting what each board will do in time.
I'm building two big decks early next year for clients and both know what to expect. All my posts will be treated 6x6's. Nothing else remains as straight over time.