I have been applying and recommending herbicides for about 35 years, including thousands of acres of 2,4-D.
I have 2 main recommendations for applying any and all pesticides.
1. READ THE LABEL. It will tell you every thing you can use it on. When you can use it, what rate to use, what growth stage you can use it, and when NOT to use it.
2. FOLLOW THE LABEL. The manufacturers have spent millions on research of their products and they know how they work. They are required to do this in order to get the label. I don't have time or money to do research on how these products will work. And, the label is the law. If you don't follow the label, you are breaking the law.
Another very important issue when applying pesticides is calibrating your equipment. I know this is something that is not done very often, especially on small equipment, but I think it's very important. Putting 2 oz per gallon of Roundup in a sprayer could equal anywhere from a few ounces per acre to hundreds of ounces per acre, depending on how many gallons per acre your sprayer is applying.
If you can't find the proper pesticides to use for your situation, contact your county agent. I know that we are very fortunate in Louisiana to have a very strong Extension service at LSU, and some other states may not have such good support, but I think its a great place to start.