Hmmmm. I ran CaCl in my tractor tires tubeless & tubed. I never noticed that much corrosion/rust to the inside of the rims. HOWEVER, what the CaCL did to the valve stem and associated parts was another story. The calcium chloride, brass valve stem and steel parts did not mix well at all. I had to install new stems every year - without fail. I would notice rusty salt water starting to leak past the stem cap and that would mean the innards were rusted and no longer held air or fluid. It was a da*n mess, to say the least.
So, if you want to put something in your rear tires - I'd recommend anything other than CaCl. I'd go dry rather than CaCl.
I use Rimguard but that's a little overboard for your location. I would, however, put some type of corrosion inhibitor in the water just to be on the safe side.