Well here is the thinking on that. Yes Calcium is very corrosive. and if it leaks out of the inner tube and into the rim, it will rot the rims.. if it was put into a tubeless tire, yes, it will eventually rot it out from the inside. Some have reported it eating the vulcanization of the valve stem and causing some leaking into the rim that you may not notice, (until it is too late) If you pick up a hole all the way thru the tire carcass and the tube, it will squirt this salty water all over your tractor as the tire rotates until you notice it. You will then fight rust on your tractor parts for some time. Ask me how I know that... The plus side of Calcium Chloride is that it is cheap and is heavier than water. Thats about it. Oh, don't get any on your shoes either, it ruins the leather. Bottom line Calcium Chloride is old school and it sucks.
Beet juice product. AKA Rimguard. More expensive by far, is only dealer applied, weighs more even then the calcium chloride solution and has non of the nasty features of calcium. It is non toxic, but it does stink. Of course it does not stink inside of the tire. You can safely put it inside of a tubeless tire. Don't let the air pressure get down too low though as it is a bit slimy and if the air pressure is too low it can result in the rim spinning inside the tire. This doesn't happen much, but it has occurred when the pressure was very very low. Overall Rim Guard is the premium preferred product to put in your tires if you can afford it.