I looked through the manual for the 3016 but didn't see anything pertaining to backhoe. Do you have the manual for the backhoe? That might provide some clue.
I am not a hydraulics expert, but I believe that generally either the 3rd function will have to have a power beyond port so it can be plumbed in between the loader valve and the backhoe, or the backhoe block should have a power beyond port that you will then route up to your 3rd function.
It would almost certainly be easier and cheaper to just use a diverter valve.