I also agree, and did my slab a few months after finishing my pole barn. I wish it had been sooner, but had to let my finances recover a smidge, and do all the prep work myself (ratwall, then level/grade, compact the snot out of the sand base, lay 6 mil poly, and 2" insulation (25psi R10), then pex tubing for radiant heating, and rebar on 2' grid (atop chairs). Doing all this prep work myself cut the slab cost nearly in half, though.
The thing about doing the slab after the building is up, is that you already have all the form work in place! And if you/builder did it right, the skirt boards are nice and level around the full perimeter so there's no guess work on the slab leveling. The only tricky part is gaining cement truck chute access to the back corners of the building, depending on your door layout.