this came fromt he wildwood survival site:
"oils from grains and plants are more prone to spontaneous combustion than petroleum oils. Linseed oil seems to be one of the worst/best candidates, depending on whether or not you want a fire.
The chemistry of spontaneous combustion is that of oxidation. An oil in its liquid form will oxidize, but there will be little heat buildup due to the limited surface area. If we spread out the oil, then there is a large exposure to oxygen, and more heat is generated. If we soak oil into a rag of some sort and confine it to some degree, we can end up with a magic (or tragic) combination which will ignite. There are various factors that do have to be properly balanced. Air needs to be able to get to the oil to enable oxidation. If there is too much air, then heat will be drawn away. If there is too little air, then there won't be enough oxidation, and the ignition temperature may not be reached. Having the whole rag/oil mass somewhat insulated also helps to retain/build heat. Lastly, there is a "critical mass" which must be established. A small piece of cloth will lose too much heat to its surroundings. One needs a large enough "pile" to make things work.
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