Yeah, the weights in the catalog specifies them at 23.6kg (52lbs). My weights are actually stamped 25kg which makes them 55 pounders but they look identical to the ones in the catalog. The larger 50kg versions (110lbs) are too large (in diameter) for the R4 rims. The owners manual states that you can install 3 per side although I have seen the online deere configurator mention 2 per side max. If you use 3 per side, this should give you an additional 165lbs per side.
BTW, the term starter weight is confusing. In some applications, the starter weight and additional weights are different. In this particular case, the weights are the same. So you use 1 weight as a "starter" weight and each subsequent weight (same weight) would be installed as an "additional" weight. The weights have holes predrilled for either application and which holes you use to fasten the weight will depend upon which application (starter/additional) you plan to use it in.
Hope this makes it a little clearer for you.