my concern with pex would be, that it would ballon over time. more so in hot summer days. another issue is making sure you run the pipe in such a way that any moisture (water) that might build up. has a place to drain out of it. meaning keeping any sags and like out of the line to a place were you could drain water out if need be.
smaller size tubing and using air nozzle to blow stuff off like mower deck. could work clearing a pipe line. but larger you go. more risk you get. with water build up.
to small of a pipe and you will limit CFM of air. or rather you may experience pressure loss when running tools that require a lot of air at higher pressures and may need to use tool, then stop, use tool then stop.
the larger the pipe you go with more likely max PSI it can handle will go down.
pending on type of crimping tool and ends, could possible limit max psi as well for pex.