RioGrande, Remember that conventional spray nozzles for ag type sprayers have a spread width of 50cms when the spray tip is 50cms from the ground and they are set at 50cms centres so that there is double coverage when spraying. That is metric and you will probably find that those 50cms measurements become 18" in the US. The outside nozzles of course go out half their distance with a single coverage. That means you need to spray on the return journey so that your outside nozzle covers the same single coverage to give you the double coverage of the other nozzles. That is standard spraying practice. Your outside nozzles should be far enough away from the plants you do not want to kill when passing them. Be aware also that there is drift, even if only slight, from the spray being applied.
There are various means you can use to reduce drift. I decided to buy rather than build due to the need for extreme accuracy when spraying my young olive trees, and took delivery about 10 days ago. It has not been off the tractor since. The boom has hoods over to keep the spray from drifting with wind turbulence due to forward travel and the effect of spray being applied under pressure. You could rig up a piece of carpet (that soaks up spray) or plastic at the edge of the outermost spray pattern if you want to get real close to susceptible plants. Remember to calibrate your spray too. There is a load of info on how to do that on the net.
I bought a model that also has a hand lance for individual spraying of trees - an absolute necessity to obtain quality fruit of all kinds. Boomless ones are used for similar purposes in large scale fruit growing, but there is an enormous drift problem and you need acreage to let the drift settle without doing any harm.