Sundown,
First of all, you can lift and/or support a PT from anywhere on the belly plate... it's all quite strong. Just block other wheels and work on a fairly level area since the belly plate is slick.
Since you would be pulling the front wheels, you can use the down pressure of the lift arms (even with bucket attached) to raise the front end up off the ground and then block it up. The center pivot may allow the front end to tilt to one side or the other, but it is not hard to deal with.
The Parking Brake on your model is very much like the Park position on an automatic transmission in that you must be at a full stop before applying it, and often may have to apply a bit of "opposite power" to achieve "full stop" and/or to relieve pressure on it to release it.
It only works on the front wheels, and once either side gets bent or otherwise in a bind from rust or debris it will not fully retract. There is a good chance you can free it up, or in worst case may have to get replacement parts from PT.
When working on hilly terrain, you will have to get used to playing "footsie" with the treadle to smoothly control your possition since these models do not have a "service brake" and the machine will still creep forward or back on a slope with the treadle in "neutral" (more so with hot oil and as the wheel motors age).
If the tractor creeps under power in one direction on level ground, you may need to adjust the cable at the hydro back assembly on the main variable displacement pump. See your manual for this procedure.
Good Luck and enjoy your "new-to-you" machine.