There is a similar pin for the lower link on my Lxx10 model that comes off to mount the Kubota backhoe. If you don't loosen it much and the tractor sits outside or in moist conditions, I expect it would get some rust and be hard to remove. Winter salt or fertilizer accumulations would do the same thing. Being that it's part of the rear axle, you may need some major heat to free it up, and I'd be reluctant to put the torch to it. There is a tab on each pin that you can grab with vise grips or use a driver to free it so the pin rotates in the hole. Would dose it with penetrating lube for a day or so first. The lower link can also simply be binding the pin, so relieve any weight on it as well. If it was rusted in place, either lube it in the future or find a drier place to keep the tractor... moisture is not friendly to machinery.