You need to get the penetrating oil in to the middle square (or triange, or I ran into a multi-fluted deal once...) shaft, not the outer sleeve. Often one end is open if not both, so you can get access to the shaft.
You will not be able to remove the safety cover, it only comes off when the pto is apart. You might need to cut it off before this is over.
In addition to the penetration oil (not WD40, but good penetrating stuff) vibration helps. This means pounding on it with a hammer. Unfortunately the shields are in your way, but if you can hammer on the ends a bit (be careful of the bearings and crosses, you want to vibrate it, not break something...) or work out any way to get some beating into it...
The oil should run down into the seam between the 2 haves of the shaft.
Obviously, you will be removing the shaft from the implement, you don't want to damage your implement, and you can get the oil in easier and so forth.
If nothing gets it apart, cut the shields off, and heat it up with a torch. That will get them apart.
--->Paul