I couldn't find my glass guy to ask him but I do know this much. The sealed glass in that door will have to ordered as a unit, they don't make them up in a normal shop. There is two pieces of glass, as you already know, and the space in between is purged with argon. At least, that is what I was told. Some of them might use nitrogen, any inert gas that'll force the moisture out would probably work. The expensive part is that they have to use tempered glass in patio doors. That is going to be an expensive unit.
I ran across a handyman site where someone had posted the same question. They advised the poster to call the manufacturer. They said that those doors are supposed to be sealed for life and there is a chance the manufacturer would replace it for free. It's worth a shot.