RV antifreeze. = if you get a leak = non toxic to plants/animals. and has some additives in it.
there should be some various additives (small little bottles) at local hardware stores, automotive stores, heck even gas stations. that can be added to coolant systems of vehicles. that might be something. never cared to try it in a tire, nor much thought about it. had antifreeze in them already, plus tubes.
over the rim = keep the metal rim under water, so the little bit of air in tire, is less likely to have direct access to the the metal of the rim and cause rusting.
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inflating tire up to max PSI, can help seat the "bead" of the tire on to the rim. if the bead of the tire is not seat correctly and good. well you just kinda have a tire that can leak or roll of the rim. but once bead is seat... for a tractor tire... time to reduce pressure.
a low PSI in a tractor tire, causes the tire to get more flat when it actually touches the ground. that large contact patch = more traction.
a high PSI in a tractor tire, causes "balloon shape" tire, were just the very center of tire touches the ground.