Start putting your wall purlins on keeping the posts plumb as you go. Go get a few rolls of "masons twine" for straight lines. These lines will not lie to you!
Use your level and string lines as you progress up to the top where your header will be. When using a string line I like to space it out where you fasten it to the corners (usually with a 2x4) off the post so that you'll need an equal thickness "guage block" to check your wall. You can move the string up with your work.
With everything as square and level as you can get it, get a good dimension that is the top of the header across to the other side (where your trussus will sit) This might have to be an average of the entire legnth of the wall, but if your real good the number will be the same the entire legnth.
Now line your trusses up on the ground, flat, so that all the edges are in line and mark your wall dimension that you measured earlier on to them. Wether you mark them at the outside of the beam (header) or the inside, it doesn't matter just as long as it is where you measured to. If you can, set about 3 or 4 at each end paying close attention to your marks, tie them togher (each group) and brace them off well, and put a string at the "tails" of these across the whole wall. From this point you can set to the string or use both the string and the marks. Every now and then have the good look at your progress and watch the truss peak, overhangs etc. Your eyes won't lie either! Take your time and be safe, I will not try to describe it here but look online or some where (the trusses should come with bracing instr.) to find out how to properly diagonally brace your trusses. Be sure that you have enough 2x4x16 around, you'll be suprised you could go thru 30pc real quick.
You may want to have a few guys there that do this for a living. good luck!