2310 Guy:
I believe your valve is labeled correctly. Here is why. The relief, if the typical spring and ball or spring and poppet type, is in the circuit right after the pump in and before the power core because the spool, when activated, blocks flow from the power core and thereby creates the pressure in the power core. The passage you see between the relief valve and the port is the passage that connects the relief vavle to the input circuit, not the exhaust circuit. Given the position of your relief valve (and the fact that most valve body relief valves let fluid flow from the tip of the relief valve through internal passages in the relief valve into the exhaust circuit), it seems unlikely that inlet pressure makes it all the way across the valve body from what you call the pump port to what you call the tank port.
Further, most PB sleeves/plugs are at the end of the power core, so that they block exhaust fluid from returning to the tank. Therefore the port with the machined boss for the PB sleeve o-ring is at the exhaust end of the power core, not at the pressure end. That is, the PB sleeve goes into the tank/exhaust/outlet port, not the pump/pressure/inlet port.
If I am correct, and you hook it up the way you plan, you will be putting full pump pressure into the exhaust/low pressure core, and the relief valve will not work because the pressure in pushing the ball/poppet into the seat rather than trying to lift it agains the spring. And, the exhaust core is usually designed for lower pressure than the power core. Full pump pressure in the exhaust core will put that pressure on the sealing o-rings and likely blow them out. That might be a blessing because if the 0rings hold then full pump pressure will build in the exhaust core and, since its walls are usually thinner than the pressure core walls, the valve body may rupture.
I may be all wrong, but there is chance enough that I am at least part right that you should get someone knowledgeable to look at it first hand before you hook it up and try it. Your pump system relief (assuming you have one) will probably protect the pump and lines, but you could damage your valve or yourself.