I'm a huge fan of PEX, but not so much for galvanized pipe in a house. Is the house already run with galvanized pipe? How does it look on the inside? Build up of minerals and nasty stuff inside of the galvanized pipe never ends and in most older homes, it's usually about 90 percent.
When installing anything new to existing pipes in a house, remember that the crud built up in that original pipe will break off and plug up the faucet and shower head.
Yes, you can attach brass to galvanized pipe with Teflon tape and not have any issues.
Be careful of sharkbite. I think there PEX lines are alright, but their brass fittings have given me issues sweating to copper. The Apallo brand at Lowes is much better and now the only brand I use.
I do not trust any slide on plumbing fitting. I keep a few half inch and 3/4 inch slide on cap fittings for temporarily closing off a copper pipe that I'm working on, but that's it. I have no faith in them being left inside a wall for the long term. They do fail from time to time and what you are left with is a nightmare of water running out a pipe full force until you can get it turned off. Then a massive demo job to get to it and then repair everything.
I use PEX for long runs and snaking it through odd angles. I use copper for all my connections to valves and threaded fittings.
Eddie