I'm trying to be helpful here, and I read through all of your posts again, but I just don't see how having more water in the system helps. It looks like you've got a very good system and a simple change would make it work really well.
For the tank on the stove, you want it to quickly heat up and then hold its temperature. You want as little water as possible without causing big swings in temperature (boiling when the circulator turns off, rapid drops when the circulator comes on).
For the floor loop, you want just enough water to fill the tubing, any more and it just means waiting for the heat to take effect.
If you want to store heat, my recommendation is to heat the slab as much as possible and store the heat there. If you heat the slab to the point that it's uncomfortable to walk on, and the shop is still cold the next morning, then we can talk about other ways of storing heat.
You already have a circulator pump. I would add a thermostatic mixing valve
Google and a
Google. This will cost about $200 for the parts but will give you a really good system.
The aquastat connects to the stove tank, and the electric leads go to the circulator pump. Put the mixing valve so the valve output goes on the intake side of the circulator. The hot input to the valve goes to the output of the stove tank. The cold input to the valve connects to a tee, which connects the return to the stove tank and the return from the floor loops. I would start off with the aquastat at 160F and the mixing valve at 110F and then adjust.
When you start off, everything is cold, the aquastat is off so the circulator is off. The stove tank water won't circulate. As your fire warms, the stove tank water starts to warm. When it hits the set point of the aquastat, the circulator turns on, and the circulator starts water through the mixing valve. The thermostat in the mixing valve adjusts the portion coming from the stove and the portion coming from the return loop to keep the water at 110F. Whatever water is pulled out of the stove tank is replaced by water coming out of the loop return.
Once it starts running, look at how it runs and make adjustments. If the circulator stops and starts a lot, it means you're pulling more heat than the stove can provide. You want to get to the point where the circulator is cycling occasionally, that's the point where you're pulling the maximum heat your fire can support. Adjust the temperature on the mixing valve until either the circulator starts kicking off, or the floor gets uncomfortably hot.
If you get to the point where the floor is uncomfortably hot in spots but you still want more heat, a bigger circulator will pull more water and more heat.
If you get to the point where the water coming back from the slab isn't cold, then your limiting factor is the ability of the slab to absorb and radiate heat. This is where you can start talking about storing heat. Although I think your best way to store heat is to warm the building, so what I would look into is additional radiator capacity.
You also want to adjust the aquastat to the point where you don't get creosote buildup. That's probably trial and error.