I almost started a new thread but thought I’d add to this one. When it comes to firewood moisture I always assumed you were drying the internal moisture out of it from it being a living tree. So how does rain and humidity come into play? I understand it would make it dry slower. What happens to a dry piece of firewood if it gets rained on? Does just the surface need to dry off? Does the wood soak up the rain and it takes days to dry
There are basically two types of moisture in the wood. One is the "free moisture", Which is relatively easy to drive out. Then there is the moisture contained within the cells of the wood. That takes more time and energy to drive out of the wood.
The point where you have driven out the free moisture and have only the cellular moisture left is called the "fiber saturation point". It varies from species to species and even from tree to tree within a species, but typically that's right around the 30% moisture content range. Air drying wood down to that point usually goes fairly quickly, assuming the wood is not in contact with the ground or constantly in a high humidity area. Getting beyond that point takes more time, or you can speed it up with heat and airflow. Getting that moisture out that is within the cells of the wood generally doesn't happen much until you remove most of the free moisture.
Once the wood has dried out, getting rained on usually just replaces some of the free water in the wood. This is more easily removed, and since it is generally a surface setting, it's even more quickly removed than if that moisture were found throughout the wood. It's usually just a matter of a couple of dry days to pull that moisture back out. The longer the wood has soaked, the longer it can take to pull that moisture back out.
Different species can dry at different rates. In general, how fast wood dries is a function of heat and relative humidity
at the stack of wood. One problem is that if the air is not moving, the relative humidity at the stack of wood can be significantly higher than in the ambient outdoor air. You need at least a bit of breeze to carry away the moisture that has come off the stack. Otherwise the drying process slows significantly.