I think the 110 is based on the prior 4x10 series that you own, but substantially beefed up in all areas. I'm not an expert on it.
As for your transmission questions - the eHydro is a HST transmission. Unless JD did something really weird, there are no clutch packs involved anywhere. HST has no relationship to automotive type automatic transmissions; it is an entirely different system. The HST pedals change the tilt of a plate that changes the amount of hydraulic fluid moved from one side of the HST transmission to another, which transmits the power. This system doesn't wear from much of anything, though it can overheat. The 3 gear ranges are manually shifted without synchros, and as long as you're at a stop when shifting, nothing should wear significantly over a lifetime of normal use.
The gear option on a 4320 has a hydraulically actuated wet clutch and has synchros on all gears. Both can wear, but they wear extremely slowly. The wet clutch should last a couple 1000 hours of use, which is probably a lifetime for a 4x20 tractor. The synchros wear too, but unless you're racing your tractor around a road course, I would guesstimate a lifetime of 5000+ hours for them, maybe even a lot more than that. Basically, with either transmission option on a 4320, I don't think you'll wear anything out. Dry clutches are more of an issue, but nothing in that series has a dry clutch.