As mentoned, an auto radiator will rupture if exposed to domestic water pressure. Also as mentioned, there are better ways to heat air with electricity than via a hot water tank and radiator. There will also be quite a bit of warm up time to get any heat out of it, and it will keep putting out heat quite a while after it is shut down. Oh, and can you say LEAD solder, so it and any potential domestic water interface is a no-no...
IF you want to put a radiator system into an existing domestic hot water system to provide instant heat after a door has been opened, you will need a fan-coil unit rated for domestic water pressure like this one
OUTDOOR WOOD FURNACE BOILER HEAT EXCHANGER 12x12 - eBay (item 170260607887 end time Sep-19-08 18:20:00 PDT) This is an example, and may not be the right size for your needs. This type are made of copper pipe and are rated to handle domestic water pressure. They are usually available from places that sell outside wood fired boiler systems and supplies. You will also need a circulation pump such as a Taco 004 or 006 or similar cartridge pump to move the water thru it. These type liquid to air heat exchangers/radiators are NOT suitable for thermosiphon. The small water tubes go across and loop back so you can get no vertical flow thru it for the cooler water to fall out the bottom and power the thermosiphon process.
IF you don't plan to pressurize it, or ever use the system to provide drinking water, it can be done with a auto radiator If the tube passages in the radiator were vertical, it can be set up to thermosiphon and circulate heat from tank to radiator without a pump. You just need to make sure the system stays full to the top of the radiator, that the top of the radiator is above the top of the tank and that there are no excessive highs or lows in the line between tank and radiator. I cool my diesel generator via thermosiphon and it circulates just fine. But if it is just for heating air, it will waste energy just setting there keeping the water warm when not in use.
If you have a few parts on your hands and are looking for a project, go for it, but it won't be any more efficient than a direct electric to air heater.
Now if you have a reasonably free source of heat, It might make sense to use an old radiator to heat air, at least it does to me

I am converting a small wood stove to an outside boiler. This will thermosiphon up to an auto radiator inside my garage to move the heat from the boiler to the garage. The system will be full of an anti-freeze mix and not be pressurized other than a small open expansion tank above the radiator. This way I get heat into my newly insulated garage without loosing any floor space to the woodstove. It will also keep all the combustables and mess outside the garage... The radiator will be mounted to a duct box that will be fed with cool air from the floor level via a squirrel cage blower under the bench.