While not exactly DIY, there is an interesting building in Seattle called Bullitt Center. It has a living building designation that means all the energy, water and sewer is produced and treated on site. One of the interesting things is that even in Seattle they can produce enough power for their needs.
It's rare that a commercial building takes an all encompassing approach like that, I'll have to check it out. A lot of energy can be recovered, once a holistic approach like that is taken.
Often, these technologies are commonly used in other parts of the world; nonetheless locally here often the biggest barrier to implementation is the building code.
A big problem in commercial buildings is heating/cooling. The energy requirements are quite large with many forms of conventional construction - get that problem under control, and your energy use drops significantly. Large scale HVAC seems particularily slow to innovate - in discussing what is considered leading edge (therefore seldom implemented) with my HVAC contractor neighbour, I found out approaches hadn't advanced much from what the company I used to work for chose to use in a custom designed building. Granted, I worked for a respected technical company (but it was not involved in HVAC), and "The Guy" in charge of ram-rodding the design (my boss) was way sharper than the average bear - but that was 20 years ago !
If the electronics industry moved like this, we'd still think an LED calculator is state-of-the-art !
Rgds, D.