I have a vermont castings (VC) resolute with catalyst and a pacific energy (PE) non-catalytic stove, here's my direct comparison:
VC - classic cast iron design is shallow and wide with top load feature, good for small rooms
pro: pretty, nice top load feature, can be used as a cook top or for making awesome percolator coffee during power outages
con: small, needs constant feeding of DRY wood, needs smaller well split 12" logs, you have to run it hot to activate the catalyst, needs more regular cleaning of ash from the firebox, easier to knock coals and ash out if loading from the front, is NOT an all nighter stove. Tends to burn from middle only, you need to clean the firebox of ash more frequently.
PE - modern fabricated design, narrow and deep firebox, double walled
pro: I can load big 18" logs, more complete burning from front to back, throws more heat to the room, firebox holds a lot more ash which is great for all nighter use
con: its big and throws a lot of heat more suitable for open plan living or large rooms
If you are buying as a supplemental heat source for the house that is easy to start in the mornings because you have nice coals the PE wins hands down. If you want a pretty parlour stove for occasional use and enjoy constantly feeding your plentiful source of small cut dry wood boards get the VC. I use my VC more for ambience and as supplemental heat during extended power failures.
Wet wood and cool smouldering fires will kill your catalyst fast. Also a recipe for creosote buildup in your chimney.