Fred,
You don't need a lot of potential to cause an arc sufficient to ignite explosive vapors. Every time you open a contact carrying current an arc is formed, some so minute they may not be perceptable, but still there. Mechanical switches depend on arc dynamics for operation. As an example take a D cell battery and short momentarily across it. At the moment you remove the short a an arc is clearly visible. Whether this arc can transfer enough energy to the vapor for ignition is a whole diffferent problem. AAA batteries will also produce visible arcs, but substantially smaller. In the instant in time when the cell phone is turned on or off with mechanical contacts which bounce, the energy storage devices in the phone (capacitors) will draw high currents sufficient to generate similar arcs to the short circuit case. If you like good puzzles, monitor this arc voltage with a high bandwidth oscilloscope and explain why the amplitude is about twice the battery voltage. Patrick J. McCleer published a book while working for Mechancial Products titled "The theory and practice of circuit protection" Contact them and they will give you a complementary copy. It's a great book for your library.