How is plastic made?

/ How is plastic made? #1  

RobertN

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I wondered if anyone here could give a description of how plastic is made?

If I had a gallon jug of crude oil sitting on my desk, how would it be processed to make a plastic broom handle, or plastic garbage sack for instance?

I have but not a clue /forums/images/graemlins/shocked.gif
 
/ How is plastic made? #2  
ABRACADDABRA!

That class was 15 years ago, I killed alot of brain cells since then. Someone will know.
 
/ How is plastic made?
  • Thread Starter
#3  
/forums/images/graemlins/grin.gif /forums/images/graemlins/grin.gif /forums/images/graemlins/grin.gif
 
/ How is plastic made? #4  
A good starting point would be to investigate "polymer science". The various characteristics of plastics are achieved by their molecular structure. It was interesting but an elective in my senior year and I never learned anything beyond basic introduction.
 
/ How is plastic made? #5  
A gallon jug of petroleum would slowly break down, oxidize and randomly polymerize, with the key word being randomly. It would slowly deteriorate into tar-like substances that are disorganized polymers. For useful plastics, we need organized polymers, that is, very repititious and predictable chemical reactions to make the polymers (plastics).

Petroleum products are related to plastics since petroleum contains many long molecules made of chains of carbon atoms that can be used as starting blocks. Depending on the shape of the molecules and the types of atoms at the ends of the molecules, as the molecules react with each other the plastic will form. In some plastics, the molecules react with identical molecules to make even longer chains (think of a bunch of identical snakes each biting the tail of another snake). This would be a very simple polymer plastic, threadlike - good for long things like broom handles. Varying the structure of the molecules can give varying properties (think of a bunch of two-headed snakes biting the tails of another snakes). This would give a branching polymer, stronger and able to cover area better (such as a plastic bag).

A summary, but more importantly, more links, can be found at:

HowStuffWorks
 
/ How is plastic made? #6  
I'm a Quality Engineer for an injection molding company and have worked in the plastics industry for 15 years. Your question is a little more complicated then it sounds.

For starters plastics can be made in many different ways. And with that their are many different polymers on the market. Because of this I will try to answer your question the best I can.

Start with the gallon jug, or for that matter any plastic bottle. The process that makes that is called blow molding. A slug of liquified material is injected with a gas to form the hollow chamber. Most plastic jugs are made of polypropylene which has a lot of lubricants in it. It's the elastic polymer which makes it flexible to withstand breaking. These are low melt materials.

Injection molding heats the resin into a soft liquid to be injected into a mold and form a shape. This process allows solid parts to be formed. It also allows you to mold harder and higher tensile materials such as nylon and other materials made for your car. Some resins have glass fibers in them which make them hard and it's the glass fiber which gives it a grainy look to it. Melt temperature here can go up to 750 degrees.

Not all plastics have carbon in them. Most do but not all. There are materials which melt like plastic, inject like liquid and after being baked act like metal. (MIM) is metal injection molding and it's expensive.

Garbage bags for instance are made like paper from pulp. The plastics are rolled through a press to a thin material and then bonded into garbage bags. You can't take a gallon jug and make it into a garbage bag. It's like apples to oranges. All different technique to it.

Everything is biodegradeable but the length of time to decompose can vary on the materials chemical property.
 
/ How is plastic made? #7  
I think he ment how to turn the "crude oil" in the jug into plastic.
But I have been wrong before
 
/ How is plastic made?
  • Thread Starter
#8  
You are right /forums/images/graemlins/grin.gif

But, I find all this information very interesting /forums/images/graemlins/wink.gif
 
/ How is plastic made? #9  
Oops. I misunderstood you.
Oil is a product in making resin but it's not the only one. When you think of oil in the making of plastic it's the lubricity of the resin which gets it's properties from oil. You also have such things as teflon in resins which give it the flow characterisitics.

As with metal plastics loose their bonding abilities when you heat them up. Because of this recycled plastics such as a milk jug can be used several times but their comes a point where oils, polymers and the like fatigue to the point where their no good. So recycling is a good idea in that respect. It's come a long way in the 20 or so years I remember when we used to just throw everything in a landfill.
 
/ How is plastic made? #10  
I'd say we've deffinately come a long way.. look at the casein (sp?) based plastics.. then.. bakelite...

Soundguy
 
/ How is plastic made? #11  
OK, this is interesting enough to make a deal. I'll share some molding information if someone else can come through with a simple (impossible?) explaination of how the resins are made.

Some years back I did a stint as a Supplier Quality Engineer focusing on our plastic suppliers. These were all molders, not raw material suppliers. I learned enough to be dangerous but not enough to start my own plastics company so here goes.

There are two primary kinds of plastics: Thermosets and Thermoplastics. Thermoplastics are your milk jugs and anything that can be remelted. Thermosets are your phenolic pot handles and anything that will not remelt. I'm sure there are many others but most fit into these two categories. Teflon may be a slightly different beast but I don't know much about it other than the interesting story I'll share later.

Thermoplastics start as a resin usually in bead form. It can be mixed with re-grind, usually mold sprues and such right at the press. Most thermoplastic molding is done in injection molding machines (presses) where the resin is heated to melt and injected under pressure into the mold. If you've put together a plastic model kit you've seen exactly what comes out of the press. You'll have your parts and all the runners and sprues to carry the material into the part mold. Other than model kits, this stuff is trimmed away and you never see it.

The molds are usually water cooled to help the cycle time. The faster you can cool the resin, the faster you can open the press and get your next shot started. Typical cycle times are well under a minute per shot. Most operations run completely automated with parts falling to a conveyor for further processing.

Interestingly enough, one of the most sophisticated molding operations in the world is supposed to be the Lego company where they make the kids toy blocks. Those simple little blocks are held to incredible tolerances. Tolerances are one of the skills of a mold maker. The mold must be made to account for material shrinkage. Note now uniform and square a lego block is. Then compare to your cheapie, county fair prize toy. You'll see parting line flash, sprue marks and various indentations where the part hasn't shrunk evenly. This is the mark of quality in injection molding.

Thermosets on the other hand, are molded several different ways. There is compression, transfer and injection. Injection is very similar but the cycle times are a little longer and the materials tend to be much "messier". Compression and transfer both start by premolding a "puck" of material. This puck is then placed directly into the mold cavity (compression) or into a transfer cavity (transfer). The mold closes and the material is squeezed into the cavity (compression) or is transferred in with a seperate ram. In either case, the internal mold pressure is generally higher with thermosets than thermoplastics and heat is now added to the mold to cure the material. Once cured the mold is opened. Thermoset parts are a little like concrete, lots of compressive strength but not as much tensile. And very heat resistant so good for pot handles.

Many plastic parts are then post-processed with machining, welding (sonic, spin etc.) or assembled.

The one experience I had with teflon was pretty cool. I visited a supplier who made small teflon rings for us. They were lathe cut from bar stock much like machining metal. Their bar stock was purchased as a raw material so I don't know much about it. This same supplier though, made teflon rings for the turret of the M1 tanks. Very cool to see. They laid up teflon blocks in ring shape on a huge sheet of plywood (the ring was eight feet in diameter or so). Again, I'm not sure how they did the bonding to create the ring from the segments. Once laid up and cured/dried they put the whole thing on a huge lathe including the plywood. Spun the whole thing slowly and cut the ring. It was neat to see and that is one thing I enjoyed most about that job... seeing products other than my own being made.

Another supplier of ours also made CD "Jewel Boxes". This was early in the life of CDs but just to be competitive it was fully automatic and would mold and assemble a CD box every few seconds. Cycle time is important in high volume!

Hope this has been useful to someone. It's fun to talk about. Now who knows how that resin is made?

/forums/images/graemlins/smile.gif
 
/ How is plastic made? #12  
<font color="blue"> Now who knows how that resin is made </font>

It is a very complex process,I work in the biggest thermoplastic manufacturing facility in the World.We make millions of pounds of the stuff each year.
 

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