I really don't know how the fluid flows in a reverse situation. There have been several instances on here where someone connected the valve backward and the valve cracked. With the second valve in neutral, and PB installed, the fluid would just flow through the valve back to the first valve. If the first valve is shifted to reverse flow to allow winch operation, the fluid now enters the PB port of the second valve. From there, just guessing. But if the fluid makes it to the motor, the expended fluid will exit the OUT port, and no fluid will flow back to the first valve. If the OUT/tank port is plugged, I see a deadhead situation.
Is there a check valve in those spools? I know there are load checks in most valves, but are only functional when shifting the spool.