I am fond of roundup concentrate (not super concentrate) and a big paint brush. Super concentrate is overkill when applied directly to the leaf. Concentrate is probably as well. I can't remember if I used up the last of my concentrate or diluted super concentrate 2:1 with water...
Roundup is absorbed through the leaf and quickly goes to the root when applied. Pouring it on the ground is a waste of product as it quickly breaks down. Likewise it is not absorbed what so ever through brown material (stalks, trunks).
Soil sterilizers will work but will kill everything around it.
Roundup applied just to the subject matter will work great. I have used a 6 (or was it 8-10) inch, thick paint brush before. It holds a decent amount of chemical and is pretty quick to apply and doesn't get the stuff where you don't want it. FWIW, I used a brush from an earlier years painting project that did not get quite as clean as I would have liked. I used it on a blackberry patch in the middle of a garden I wanted out. First application took out 90% without harming anything around it. I should repeat the process on what is still left alive.