From here:
Avgas - Wikipedia
"100/130 avgas has an octane rating of 100 at the lean settings usually used for cruising and 130 at the rich settings used for take-off and other full-power conditions."
Yes, using aircraft octane performance ratings you can get those numbers.
If you test the exact same sample, using automotive octane ratings, (R+M/2 method), you get like 96 octane. Which is doable now in unleaded.
The vast majority of aircraft are low compression, and do not need high octane fuel. So, even if they kept 100LL for the high compression engines, 80% of the lead could be eliminated, by switching the rest to regular unleaded.