At least in PA, as far as I know, there is never any requirement to be licensed to
work on any voltage. However, there are contractor licensing requirements if you call yourself an electrician or charge for services. And because only licensed contractors get to work on utility systems, that circuitously covers them at those voltages.
I've spent most of my career working on high voltage hardware, and while we as a company had training requirements, that was a matter of controlling our own liability and safety, and not a matter of licensing requirements.
Ever seen someone shock themselves on a 40,000 volt DC power supply? I have!

And I'm not talking about wimpy low-current TV tube supplies, either... these were capable of delivering 50,000 watts or more.