The 6 x 6 seem to be straight...seems like they use the center of the tree and not an off-center cut--I guess that allows more equal expansion/contraction with moisture changes. I just placed some 16 foot ones that were very straight. I had the same concern as you but they were perfect. I realize 20' is even harder to get straight.
Also, be careful about the type of pressure treating you get. I have been told by several local goat and sheep farmers (inlaws included) that the new ACQ has too much copper and can be dangerous or even fatal to goats/sheep. I got the older CCA for this reason. Lumber yard said the same. I do NOT know if it is true or an old wive's tail, but I figure I would stick with the CCA. They were also a fair amount cheaper!
Hope your project goes well, keep us posted.
Peter