Typically propane bottles are not painted on the inside and when you use them for air you can often end up with condensation inside the NEW air tank which promotes rust. This is bad for a couple reasons: 1. can cause tank failure and 2. can put rust into whatever uses the air.
If you clean and coat the inside of the tank with a rust proofer you will eliminate the problem. You don't hear much about exploding air tanks made from propane bottles for several reasons among which are: 1. the builder user was not in shape to talk about it, 2. it doesn't happen very often (once is one time too many if anyone gets hurt)
If you clean and etch the inside of the tank and use epoxy paint or the Rustoleum brand "hammertone" rust proof paint or "Kreme" (sold at motorcycle shops for leak/rust proofing gas tanks) The inside of the tank will not rust.
Some folks have surplus tanks avail with the old style fill or whatever and have no particular use for them. If you have means to cut the tank: 1. plasma, O-A torch, saw, or whatever they make good sturdy fairly long lived BBQ grills and smokers (skip the above listed coatings for the inside and consider no coating or a super high temp paint for the part next to the fire.
Observe proper safety practices when cutting a tank. filling with water except for a small "bubble" of air and rotating the tank so you are torching where the bubble rests is one method that is used. Another is putting some dry ice in the tank and putting the valve back in slightly opened and oriented to be on top. The dry ice (frozen CO2) sublimates (goes directly from solid to gas without passing through liquid stage) and is heavier than air and fills the tank forcing out all the air and its oxygen. If the tank has been well aired out it may stink like propane (due to the mercaptan or other odorant added to make leaks obvious) but not have any propane in it so the above safety precautions are not absolutely mandatory in all cases but do be careful.
Anyway the tanks, especially in 20# and larger sizes make good grills and smokers. You can use the smaller bottles (20#) mo' betta by using one for a fire box and plumb the smoke to another that holds the meat. Get inventive!
P.S. Sorry HIGHBEAM I didn't get notified of your post mentioning BBQ till after I posted about that.
Pat