I was fixing to jump in and say "always CRIMP anything bigger than a #6AWG and CRIMP-then-SOLDER anything smaller"; but then I read PILOON's response and I agree on the soldering only when it is something expensive that you might want to re-use later, as you can apply a little heat and salvage the connectors.
On anything that is intended to be permanent and not likely to ever be taken apart, the following applies :
On the small stuff, crimping-then-soldering is absolutely the best way to go; the crimp provides a strong mechanical connection and the solder seals everything up against moisture and corrosion.
On big stuff, vibrations and occassional high heat will soon weaken a soldered bond and therefore a good strong crimp is by far best.
I have a set of jumper cables made out of 3000 volt silvercoated fine wire railroad cables that are about 75' in lenght. Nice thing is they are heavy enought to jump a loco with completely dead batteries. 500 amp rated clamps to complete the job. USAF EMD SW-8 jump started a NASA Alco S-2 without batteries even hooked up and no heating of the cables.When I worked for Norfolk-Southern, we were forever more having to "jump" locomotives; they usually idled all the time, but when one was shut down for whatever reason, you may as well expect to have to jump it.
The Southern engines all had those huge jumper connections at each end of the engine, right alongside the big M.U. cord.
By plugging the connector-cables between each unit, one could jump-start for instance the fifth unit from the first unit, so long as no "foreign" units were in the mix.
Along the same line of thought, the local Ford garage has their service truck permanently hard-wired with a set of jumper-cables.
The portion of the cables that connect to the service truck battery have copper lug-terminals crimped on and are bolted on to the battery terminals.
The cables are routed through the grille and are neatly wound around a purpose-built bracket.
The "alligator" ends are clamped onto an insulated rod when not in use.![]()
USAF EMD SW-8 jump started a NASA Alco S-2 without batteries