I think there is little to worry about in terms of the toxicity of Calcium Chloride. Here is a short exerpt from Wikipedia:
Unlike the more-common sodium chloride (rock salt or halite), it is relatively harmless to plants and soil. It is also more effective at lower temperatures than sodium chloride.
It is used in concrete mixes to help speed up the initial setting. However, chloride ion leads to corrosion of steel rebars, so it should not be used in reinforced concrete.
It is used for dust control on some highways, as its hygroscopic nature keeps a liquid layer on the surface of the roadway, which holds dust down.
Calcium chloride tastes extremely salty and is used as an ingredient in some foods, especially pickles, to give a salty taste while not increasing the food's sodium content. It's also used as an ingredient in canned vegetables to maintain firmness.
Used as an additive in plastics.
Used as an ingredient in the Cadbury Caramilk chocolate bar (reason unknown)
Used as a drainage aid for wastewater treatment.
Tire ballast