Never seen that show. I did once see a quart jar of what a state trooper (different state from mine) said was good moonshine and he did poor a little in a lid and light it; got a pretty blue flame. But no way I'd risk drinking any of it.
My dad had one uncle who was showing his new pistol to his best friend when it went off and he accidentall killed his best friend. He did a year in the state penitientary for manslaughter and became an alcoholic when when he got out. Then he was still a young man when he got some back moonshine, was paralyzed for awhile, eventually regained use of his arms, but had to wear braces on his legs and use crutches the rest of his life. There just ain't any drink good enough to be worth taking that chance.