In pre-electric light days (and even later in houses off the grid), some houses had acetylene lights. To make it even more dangerous, some of those houses (maybe all) generated their own acetylene. Also, way back when .... car headlights ran off self-generated acetylene. And then there were the miner's helmets that had headlamps that ran off gas created by dropping water on to Calcium Chloride rocks.
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I think you mean Calcium Carbide. Calcium Chloride is what is mixed with water to prevent freezing when putting in tractor tires in days of olde.