Rusty,
An automotive system is the same as a radiant system. The "coolant" in a car absorbs heat from the hotter interior surfaces of the engine block and gives it up to the cooler interior surfaces of the radiator tubes. In a radiant floor, the "coolant" absorbs heat from the hotter interior surfaces of a boiler and gives it up the cooler interior surfaces of the radiant tubing. Same thing. In both cases energy is simply being transported between two objects that are at different temperatures, by a fluid. The energy is being absorbed and released by conduction.
Principal is the same but the conditioning elements (physical make up of the coolant) in a cars system has different conditioning (anti corrosion inhibitors etc) materials for the engines and mixed metals (copper, aluminum, rubber hoses, cast iron, plates brass materials all in cars) while PEX and usually Steel/Iron/Copper for fittings and the water in a boiler is designed to last 10 or 20 years vs 5 years or 100K miles in car...
The thermal efficiency of the Copper, Steel, Iron & Aluminum in cars is much better than those in the Home Boilers as well & PEX is pretty poor at transmitting the heat from the boiler to the floor. BUT it lasts much longer in the concrete vs Copper or Aluminum which would corrode and leak in no time buried inside a concrete slab...
The Freeze Thaw should be OK on the PEX the Concrete however maybe develop some cracks or loose areas and if it was real good concrete the PEX may have compressed some thinning the walls at weak spots in the concrete as it lets the PEX expand MORE to those weak areas.
Mark