I can only provide anecdotal evidence, but I have been shocked by 120 VAC lines a few times and while bad enough, on dry skin, I sure was glad the path was across fingers and not thru my heart area. I got bit once on a 330 Volt DC line once. This power supply was probably current limited to about 500 milliamps or less, but still it knocked the Pizz out of me and made me ill for some minutes.
The current path was thru my fingers and out near the elbow of the same arm.. The other hand was in my pocket as all good TV servicemen are taught. Servicing Televisions was a dangerous job when I was a young man, before the solid state revolution when the chassis of television sets were made of steel, and full of vacuum tubes. I never got hung on the 800 volts or so on the final tubes that drove the horizontal deflection (flyback circuits) as those were truly lethal, but changing one of the small tubes in a tuner section got me bit with the 330 volts on a feedthrough capacitor sticking up thru the tuner chassis.
I have worked on transmitters with over 3000 volts on the finals and power supply's good for an ampere of current, but you always take serious precautions with things like that, but it was the little receiver B+ voltages around 300 volts that could get you.
I cannot imagine grabbing on to 220-240 volts AC that is current limited by a 200 amp breaker that will blow after a couple of minutes of frying your butt. I have seen old electricians with calloused dry hands touch 120 volt circuits to test them but I have never seen one grab onto 240 volts to test it that way. Twice the voltage with a given skin resistance equals twice the current flow, plus the higher voltage can more easily break down your skin resistance to increase current flow to an even greater degree.
I have heard some electricians say that a 220 volt shock is more likely to "blow you loose" from the circuit with greater damage but a 120 volt shock is more likely to hold you on to the circuit, and kill you. I don't know if this is true, as the 120 volt shocks I have received with dry hands and not thru a vital region of my body, were enough for me. I have never been shocked by a 220 VAC circuit and I prefer it stay that way.
I have been "shocked" by the 48 volt battery supply's that act as backup for large PBX telephone systems. But you have to be sweaty to feel it. With dry hands you cannot feel a thing. These supply's are capable of instantaneous currents in the hundreds of amperes, and you are in danger of serious burns if you place a metal object across them. A wrench will turn white hot and melt in a couple of seconds, if you are in front of the fusing. There is also a great danger of explosive hydrogen gas release.
Ain't electricity fun. :shocked: