The voltage (difference of potential) is what drives the current and the current is what does the damage. If you scuff across a rug, you can charge your body to several thousand volts and yet you are unharmed when it discharges in a small spark since there is such a minuscule amount of current involved with the static charge. A larger static charge might very well have enough amperage available to injury or even kill you...lightening being the most common example of this. From
Lightning "The average lightning stroke has a peak current on the order of 30,000 amps. But some discharges, especially those that are totally within the cloud, are only several thousand amps. On the other hand, superbolts do occur, occasionally reaching 300,000 amps or more. The electrical potentials involved in lightning discharges can range up to 200 million volts."
Anytime you see a high voltage sign, trust that there is enough amperage available to cause you injury and /or death. According to the 2002 National Technology Transfer's manual, Electrical Safety Requirements and Procedures, the average male can perceive electrical flow from 1 milli-ampere (mA - also called milliamps) - 10 mA (0.001 amps - 0.010 amps). From 3 - 10 mA the sensation is very painful. At 10 mA is the paralysis threshold, where you can't release your hand grip on an object. At 30 mA (0.030 amps) is the respiratory threshold which causes a stoppage of breathing and can be fatal. At 75 mA (0.075 amps) is the fibrillation threshold where heart action is discoordinated. Fibrillation can not be treated with CPR and at this state it can be fatal if a defibriillator is not applied within several minutes. Typically, the thresholds for women are slightly less.