All VERY GOOD posts!!! (rare in an internet forum!)
I'll add o a few (but you've probably experienced a couple already)
Engage the PTO at a low RPM (reduce the shock load to the tractor's PTO), but keep your foot or hand near the throttle if the engine starts to stall (give it a bit more fuel if that happens).
By now, you know the cutter will make a lot of noise and vibration initially...and you'll hear the "bang" when the blades pivot out.
Also remember it takes quite a while for them to spin down (my old Land Pride takes close to a minute)...still fast enough to throw debris out. Use caution and stay on the seat if possible.
Kebo wrote about watching the temperature gage...yes, do this. I keep a small paint brush (about 2" wide and the bristles cut down to 3/4-1 inch) to clean the grills. Bush cutting is a dirty dusty job!
Speaking of dirty dusty...you're breathing the same crap that is clogging your radiator grills...think about a dust mask...goggles (and, of course, hearing protection).