Well by now I wouldn't be patient anymore as my thought's would be along the line of once this thing is off it's not going back on. I would take a zip cut wheel on an angle grinder and cut the collar off and what ever else is necessary to remove the yoke. New yokes for compact utility sized equipment are not that expensive.
This seems to be an overly severe solution. If the OP could take some pictures of the tractor end of the PTO we might be able to identify the brand and give more information. Just a guessing game this far.
Agree with above suggestion to lube up the quick connect, engage the PTO for a minute or two. With PTO still engaged, shut off tractor, which will hold the tractor PTO shaft from rotating. Then, with both hands, pull back on the collar, and hopefully the coupling will come off.
With some good pictures, we could evaluate if the cover over the tractor end u-joint could be disconnected and slid back, exposing the u-joint. Separate the u-joint and the OP will have good access to surmise the problem.
Really early to start chopping on the PTO with a grinder?
I used to get really impatient dealing with issues on used equipment but, learned to step back, take a deep breath, and re-evaluate the situation. Not everything can be fixed with a 10# sledge hammer.
Still betting that the collar has to be pulled toward the implement to release.
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