There is some type of mechanism that keeps fuel from coming out if no appliance is attached. I found that out the hard way years ago... I left the valve open for a few months, then put a wrench on it and turned the valve out. I'm lucky I wasn't leaning across the top, the valve shot up about 30 feet and would have taken me in the face.
Since others have tried it first I may resort to the .308 method. At least if something goes wrong I will be 100 yards away.
I also found out recently that there is no approved way of getting rid of all of those disposable propane tanks I've thrown out over the years. Apparently they don't want them in trash incenerators... go figure.