I found a good manual to help change some operating parameters
Table Of Contents - Alpine ALPB Installation, Operating And Service Instructions [Page 4]. Read through it a few times to get familiar with the terminology and how to adjust some settings, especially pages 83 on up. Some pictures or a drawing of the piping layout would help also. A few comments:
If the primary loop supply and return are separate or tied together at the end of the run would make a big difference how the system operated. The supply to each heating manifold should tee off the SUPPLY of the primary loop, into the zone pump, into the manifold, through the loops, back to the return manifold, into a closely-spaced tee (3" from the first tee in the SUPPLY of the primary loop). I don't know why a mixing valve is installed at the manifold, so follow the suggestions below before any physical changes to the system.
You are able to have different temps for DHW and heating loops. I am almost sure the heating loop temps should be lowered to maybe 150° vs 180° where they are set now. If your mixing valves are set to 110°, they have no way to reach this temp without cooler water available, set them to 140° (which is fine for under-floor heating). Condensing boilers are the most efficient when the return water temps are near the acceptable minimum (near 130°)...your controller will let you know when operating at this range.
The DHW loop should remain at 180°
The boiler may be over firing also. The controller has settings to change the maximum BTU output for heating and DHW, I wouldn't change these yet, but may be necessary to match output to required heat load for the house.
The regulator should probably be checked to verify that the input pressure to the boiler gas valve is correct.
All these changes can be set back to where you started if you keep a record of everything you do. It's usually best to try this before ripping things apart and repiping the system!
It's a lot to digest...and if it doesn't work "It's not my fault, I am only 58". :laughing: