The Case 75 HP is just a different color but same tractor as the New Holland T4.75 that I was considering buying. They, and others, use a "Particulate Matter Catalyst" (PMC) to clean the exhaust instead of a DPF. Be aware that they still require the engine to run at high rpms to keep the exhaust system hot enough to burn off the soot! Regardless of whether a tractor uses DPF or PMC to meet Tier 4 requirements, BOTH need to be run at high rpms, with minimal idling. Quoting from the New Holland literature the dealer gave me: "The (PMC) simplest system around, it requires minimal operator intervention with fewer occurrences of regeneration than competitors with a DPF".
What they're really saying is that the PMC system is actually "regenerating" continually, burning off soot as it runs through the catalyst. That's why it too has to run at high rpm, to keep that catalyst hot. Whereas a DPF system such as in my Kubota only regenerates after a certain amount of soot buildup in the DPF is detected.
I know of no Tier 4 tractor under 80 hp that uses DEF. They use either a DPF or PMC but none require DEF usage.