I worked briefly for NASA in 1963 doing this for critical assemblies that went onto the tower next to the rocket to keep the tanks topped off until the moment of launch. They told me it was called "torque painting" and they used specially formulated paints that had an odd mix of many obscure ingredients, the purpose of which was to make it practically impossible to imitate the paint. This torque painting was done to make Soviet sabotage less likely and more easy to detect after the fact if it did happen. The paint was very special, yes, but it was put in ordinary nail polish bottles.
The reason I was hired to do this was that I was only 6 years old at the time, and could fit into small places. These assemblies were too big to reach into and too compact to crawl into for adults. I crawled in with a mirror and a paint bottle. Engineers outside had me position the mirror and point to fasteners as they guided me, and when I was pointing to a fastener that needed torque paint, they'd say "Yes, paint that one", and we worked our way through the whole thing. I got some kind of paper certificate from NASA (which was a pretty young agency at the time) and we kept it posted in the kitchen for years.