Before we moved to our new house a few years back, I had to clean up our current place. This included hauling 17 old propane tanks away (these were all on the property when we got there). The landfill refused to take them as they were. The valves either had to be removed, or they have to have holes punched it them. Most of the tanks were small 5 or 7 gallon tanks, but 7 of them were 100 pounders. All of them had a small amount of gas in them. I took them all out to my local shooting area (not a range per se, just a small canyon where shooters go), lined them up, and put at least two 30-30 rounds through each one. None of them went boom, and only two of them fell over due to gas venting from the first hole. The only 'exciting' thing that happened was when I shot one of the 100 pounders near the bottom. It did create a pretty cool spray as the liquid came out and turned to vapour. But other that it was mostly a non-issue of popping holes in them.
Good luck.
NV