Most people just position the rebar so it's in the middle area of the pad. For most applications, this is fine. For the best results, the rebar should be at the 1/3 point from the bottom. Think of concrete as a beam going across a span, and it wants to sag in the middle. Putting the rebar at the lower third point of that beam will give it the most support at holding it stiff and flat. Rebar holds the concrete together. It doesn't add an PSI to it.
Almost every pad is poured with too much water. The excess water will evaporate and leave a void behind where it used to take up space. You lose volume to our concrete when that excess water goes away.
Most concrete crews will add as much water as they can get away with because it makes it so much easier to spread the concrete. A good contractor will stop this, but most also want to get the job done as quick as possible, so they allow it to some degree. On commercial jobs, they test the concrete by putting some of it in a small pail and then flipping it upside down to make a sand castle. If the concrete comes out of the pail and remains in shape, you have the right amount of water. Most pails to do this are about a quart. Google "Slump Test" if you want to learn more.
To gain the most strength out of your concrete, you use the smallest amount of water. Adding Portland Cement to the mix will also increase your PSI. Making your pad thicker will increase PSI. After that, it's very hard to make noticeable gains for a reasonable amount of money.
Wire mesh works better then rebar at holding the concrete together. Unfortunately it is impossible to keep the wire mesh in the middle of the pour. Liars, I mean concrete contractors, will tell you that they lift it up while they are spreading the concrete and you are supposed to believe that it stays in the middle of the concrete while they walk on top of it. This also happens to rebar without chairs. Anybody pouring concrete without chairs is a hack and should be fired on the spot, unless it's such a small area that you can actually add the rebar or wire mesh to the concrete and never on any of it.
Most rebar is done on a 24 inch grid. Tied together and the chairs are installed close enough together that the rebar is flat. If you tie your rebar really well, and overlap each stick, you can go farther out with your chairs. I won't say what that distance is because I've never paid any attention to it. I just put the chairs under the rebar after it's all tied and decide on where they go one after the other.
I prefer rebar on a 18 inch grid. It's not a lot more rebar, and you can still walk through it easily while spreading the concrete, but I think adds enough to the pad to make it worthwhile. All concrete cracks, but if you have enough rebar in it, and you use the correct amount of water, there is no reason that you have to see those cracks!!!