Glad to hear it's gonna be trussed, that's HUGE for any serious (more than about 8') span.
My shop used to be a 36x48 x 12' pole barn - the original roof was 2x12's on 12 foot centers, 2x6 purlins on edge and heavy galvanized tin. I didn't want poles in the center, so I converted each 2x12 into a truss using 2x8 horizontals and 2x6 web - I used pieces of 1/2" ply (smallest was 2'x2') on both sides of each joint. Generous amounts of Titebond glue, did each intersection one at a time using every clamp I owned to tie it all together, then played "john dillinger) with a nail gun and ring shanks, let cure for a day before clamps came off;
The last joint was tying the bottom chord 2x8's together. I left 1/2" gap between the two pieces of 2x8, then chains/comalong between outer poles and closed the gap, did the plywood sandwich thing, etc -
At that time I still had the tin roof; that winter we had our usual wind storms (measured @ 70-80 mph) - a couple of the tin pieces folded back, but those trusses never moved.
Since then I had the house re-roofed, and had the roofer add cross ties between framing and sheath the shop with 5/8 CDX ply and 30 yr. three tab, same as the house. It's kinda nice to hafta open the door to know if it's raining, instead of just reaching for the ear muffs
Before I had the slab poured I first scraped all the "animal leftovers" down to bare clay, then AFTER the original rafters were trussed I sliced off the nails between 2x12's and 6x6 treated poles, and dropped 2 of the 3 interior poles out, leaving the last pole to help support a mezzanine across one end of the shop.
This is all a long-winded way of saying that you should do fine the way you're going; I tend to "think 4-5 times, measure 3-4 times, run thru the plan 2-3 times, lay out everything I might need to reach without letting go of whatever I'll need to hold, measure again, and (hopefully) cut once - this has saved me pain more than once, since 99% of the time I'm working alone.
Here's a couple pics I found that shows my truss connections... Steve