Electrician son setting here beside me. His suggestion if you want 220 at your shop using the exsisting wire is it can be done. We are just guessing that the #10 wire you used to run the power does have 2 insulated and one bare wire. What you would do is change out the 110 breaker to a 220 breaker in your power supplying breaker box. (from house breaker box). Using the two insulated covered wires for your power legs and bare wire to ground. In you shop breaker box, you would take the Neutral (white wire) off the ground busbar and connect to the opposite (Positive) busbar than the one the Positive, (black wire) is hooked to. If there has been a jumper wire ran to connect both busbars, this jumper wire must be removed. Then you would use another bare wire and connect to the ground busbar,( In place of where your removed the white neutral wire), and connect to a ground rod driven into the ground. Your switch panel should now have 220v, but still retain the original 110 to any current breakers that had previously been installed. It would then be a simple matter of installing a 220 breaker and wireing in a 220 outlet. Now the size breaker you would be able to install would depend on how far the 110 wire from house to shop is, as well as what other power demands are required that are being used in the shop. You would also need to factor in the power demand of your shop when installing a 220v breaker in our house switch box. You will most likely be limited to a 30amp breaker and about 100ft of run to supply 220v to your shop considering you only have #10 wire already ran to your shop