Look at the way starter fluid works. It is much much easier to compression ignite than diesel. If you spray in several seconds of it into intake THEN crank, the first cylinder will get the majority of the shot. The either ignites while the piston is on the way UP making combustion pressure rise dramatically. The diesel that is coating the piston ignite raising the cylinder pressure even more as the piston continues to rise up. The normal fuel is then injected and immediately ignites rather than the normal slow controlled ignition. If you are "lucky" the engine starts. If you are "Unlucky" and sprayed in too much fluid or had all of it in 1 cylinder, you can blow the ring lands off and crack the piston skirts even bend the connecting rod.
Ether addicted engines have one or more compression ring lands hammered off. Pull some down and study them. I have, that's why I only will ever spray ether into a cranking engine so the ether is spread across several cylinders and the dose is limited. But that is only as a last resort.
Other folks have other opinions and as they say YMMV
jb